James "Jim" DeWolfe (born May 14, 1949) is a former political figure in Nova Scotia, Canada. He represented Pictou East in the Nova Scotia House of Assembly from 1998 to 2006 as a Progressive Conservative.
He was born in New Glasgow, Nova Scotia, the son of William Elliott DeWolfe and Hazel Macdonald, and was educated at St. Francis Xavier University and the Technical University of Nova Scotia. In 1968, he married Diane Mary Breen. He was employed by the Bank of Nova Scotia from 1967 to 1968 and then worked for the Nova Scotia Department of Mines and Department of Mines and Energy until his election to the provincial assembly in 1998. DeWolfe retired from politics in 2006.